Advanced Materials
http://onlinelibrary.wiley.com/doi/10.1002/adma.201203230/abstract
A one-pot polymerization strategy is put forward for producing 1D
polymeric nanomaterials directly from a single inimer. An inimer
bearing an NMP initiating site is polymerized in the presence of a RAFT
CTA to form a pearl-necklace structure constituted of hyperbranched
polymer “pearls”. The obtained 1D nanorods show high regularity
evidenced by the long-range order in small angle XRD patterns and the
formation of liquid crystalline phases.
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