Transformations of Alkynes at a Cyclotriphosphato Ruthenium
Complex
Keiichiro Kanao,† Yousuke Ikeda,† Kazuhiro Kimura,† Sou Kamimura,‡ Yoshiaki Tanabe,§ Yuichiro Mutoh,† Masakazu Iwasaki,∥ and Youichi Ishii*,†
This paper reports use of Ru(II) with the P3O9 ligand for conversion of alkynes to alpha-keto-carbenes; Fischer carbene complexes are also formed from the alkynes under certain conditions. Still this is an interesting transformation.
http://pubs.acs.org/doi/abs/10.1021/om3009926
Keiichiro Kanao,† Yousuke Ikeda,† Kazuhiro Kimura,† Sou Kamimura,‡ Yoshiaki Tanabe,§ Yuichiro Mutoh,† Masakazu Iwasaki,∥ and Youichi Ishii*,†
This paper reports use of Ru(II) with the P3O9 ligand for conversion of alkynes to alpha-keto-carbenes; Fischer carbene complexes are also formed from the alkynes under certain conditions. Still this is an interesting transformation.
http://pubs.acs.org/doi/abs/10.1021/om3009926
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