Reticulated Nanoporous Polymers by Controlled
Polymerization-Induced Microphase Separation
Myungeun Seo and Marc A. Hillmyer
Polymerization-Induced Microphase Separation
Myungeun Seo and Marc A. Hillmyer
http://www.sciencemag.org/content/336/6087/1422.full
In this work, microporous polymer networks were synthesized via RAFT polymerization of divinyl benzene and styrene, where the RAFT CTA was a PLA-functionalized trithiocarbonate. The PLA plays its role in giving rise to microphase segregation during the polymerization, and is then etched away by treatment with methanolic/aqueous sodium hydroxide.
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