Thursday, February 7, 2013

Abnormal NHC silyl derivatives

Lewis Base Stabilized Group 14 Metalylenes
Amit Pratap Singh, Prinson P. Samuel, Kartik Chandra Mondal, Herbert W. Roesky,* Navdeep S. Sidhu, and Birger Dittrich* 

This paper reports the synthesis of an abnormal NHC-Si derivative by NHC exchange.  The authors speculate that the abnormal NHC is a better electrophile and nucleophile compared to the conventional NHCs. 

No comments:

Post a Comment