Journal of Polymer Science Part A: Polymer Chemistry
A synthetic methodology is described for the preparation of core–shell 
nanogels by reversible addition-fragmentation chain transfer. 
Well-defined macro chain transfer agents (macro-CTA's) were prepared in a
 first step using monomers that yield sensitive polymers. In the second 
step, a crosslinker alone or with the addition of a functionalized 
comonomer were used to form a crosslinked core. The ratio of crosslinker
 to macro-CTA is crucial to yield nanogels. 
 
 
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