Sunday, July 8, 2012

Electron Donor and Acceptor Spatial Distribution in Structured Bulk Heterojunction Photovoltaic Devices Induced by Periodic Photopolymerization

Langmuir
 
http://pubs.acs.org/doi/abs/10.1021/la3005618

 Donor and acceptor spatial distributions were directly formed in a surface relief grating of structured bulk heterojunction (BHJ) photovoltaic devices by simple periodic photopolymerization. Enhanced photocurrents were observed in the structured BHJ photovoltaic devices and formation of the D/A spatial distribution was confirmed by Kelvin probe force microscopy. This technique enables the fabrication of structured BHJ photovoltaic devices with solution-processable organic semiconductors, and has tremendous potential for controlling D/A spatial distribution in organic optoelectronics devices.

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