Wednesday, October 24, 2012

One-Pot Cascade Synthetic Strategy: A Smart Combination of Chemoenzymatic Transesterification and Raft Polymerization

Shiqi Wang, Changkui Fu, Yun Zhang, Lei Tao, Shuxi Li, and Yen Wei

In one pot, enzymatic transesterification (by Novozym435) was performed between a primary alcohol and an acyl donor ligand (2,2,2-trifluoroethyl methacrylate) followed by RAFT polymerization of the resulting product. Kinetic studies, GPCs, and NMRs were obtained to characterize and monitor the reaction.

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